How to pronounce greek letters
The greek letters \(\xi\) (“xi”), \(\eta\) (“eta”) and \(\zeta\) (“zeta”) are often used in textbooks as counterparts to the latin x,y and z. This needs practice. All the more so that there also are the two greeks \(\chi\) (“chi”) and \(\omega\) (“omega”).
I’d like to make a table for this:
| xi |
|
| eta |
|
| zeta |
|
| chi |
|
| omega |
|
For practice, I start with a widely forgotten formula by Messieurs Dulong and Petit
\[\left({\eta}^{\xi} - 1\right)\,\zeta\]
How on earth do you pronounce that? Here we go
eta power xi minus 1 times zeta with xi in Celsiusandeta zeta being constants
Included is the hint that the xi-\(\xi\) is a temperature measured in degree Celsius. But what are the constants eta-\(\eta\) and zeta-\(\zeta\)?
The formula of Dulong&Petit
I define a function which includes the sought-for numbers
(defn dp-formula [Celsius]
(calcbox [((((eta power xi) minus 1) times zeta)
with
[xi in Celsius])
[and [(1 comma 0 0 77) for eta]]
[and [(2 comma 0 2) for zeta]]]))This reads as
(kind/hiccup [:blockquote (:hiccup (dp-formula 0))])eta power xi minus 1 times zeta with xi in Celsiusand1 comma 0 0 77 for etaand2 comma 0 2 for zeta
The formula prints like this
(tex (:calc (dp-formula 'xi)))\[\left({1.0077}^{\xi} - 1\right)\,2.02\]
I can now also calculate a number, e.g. for 100 °C
(:calc (dp-formula 100))2.3298794924642854But what does this number mean? It is degrees per minute. In 1817, Dulong and Petit measured the rate of change with time of the indicated temperature on a previously heated mercury-in-glass thermometer with a spherical bulb placed centrally in a spherical enclosure held at zero degrees Celsius.
These were their measured values
| °C | °C / min |
|---|---|
| 80 | 1.74 |
| 100 | 2.3 |
| 120 | 3.02 |
| 140 | 3.88 |
| 160 | 4.89 |
| 180 | 6.1 |
| 200 | 7.4 |
| 220 | 8.81 |
| 240 | 10.69 |
So, when the thermometer was at 100°C, within the first minute it lost 2.3 degrees due to radiation. In that case, their formula was pretty accurate. But a man named Pouillet used the formula to estimate the temperature of the sun, got a value of some 1700 degrees, and that seemed pretty low to a certain Josef Stefan. He re-published the above data and proposed his famous fourth-power law on the relationship between heat-radiation and temperature on pages 391-428 of the “Sitzungsberichte der Kaiserlichen Akademie der Wissenschaften, Mathematisch-Naturwissenschaftliche Classe, Neunundsiebzigster Band, Wien, 1879”.
The law of Stefan
(defn stefan-law [Celsius constants]
(calcbox [((((chi plus xi) power 4 )
minus
(chi power 4))
times
omega)
[with [xi in Celsius]]
[and [[chi omega] being constants]]]))\[\left({\left(\chi + \xi\right)}^{4} - {\chi}^{4}\right)\,\omega\]
chi plus xi power 4 minus chi power 4 times omegawithxi in Celsiusandchi omega being constants
We need to set omega-\(\omega\) to one six billionth. The other constant is given by the absolute zero temperature, chi-\(\chi\) = 273.
As an exposition, we calculate the fourth-power of 273. The result is a pretty big number.
chi times chi times chi times chiwithchi equals 273
5554571841I can imagine that in the 19th century, without having computers, to fit some data it took considerable guts to take on a fourth power law.
(defn stefan-law-numbers [Celsius]
(calcbox [((((chi plus xi) power 4 )
minus
(chi power 4))
times
omega)
[with [xi in Celsius]]
[and [(one (6 billion) th) for omega]]
[and [273 for chi]]]))chi plus xi power 4 minus chi power 4 times omegawithxi in Celsiusandone 6 billion th for omegaand273 for chi
\[\left({\left(273 + \xi\right)}^{4} - 5554571841\right)\,\frac{1}{6000000000}\]
Stefan’s Law passes the first test in fitting the data as well as the old model.
| °C | °C / min | D&P-formula | Stefan law |
|---|---|---|---|
| 80 | 1.74 | 1.71 | 1.66 |
| 100 | 2.3 | 2.33 | 2.3 |
| 120 | 3.02 | 3.05 | 3.05 |
| 140 | 3.88 | 3.89 | 3.92 |
| 160 | 4.89 | 4.87 | 4.93 |
| 180 | 6.1 | 6.01 | 6.09 |
| 200 | 7.4 | 7.35 | 7.42 |
| 220 | 8.81 | 8.9 | 8.92 |
| 240 | 10.69 | 10.71 | 10.62 |
With his new formula, Josef Stefan estimated the lower bound of the temperature of the sun to be around 5600 °C which means he was pretty much bang-on within some 100 degrees.